- Surfactant-mediated desorption of polymer from the nanoparticle interface. B Cattoz, T Cosgrove, M Crossman and SW Prescott. Langmuir, 28(5), 2485–2492, 2012.
The surfactant-mediated desorption of adsorbed poly(vinylpyrrolidone), PVP, from anionic silica surfaces by sodium dodecyl sulfate, SDS, was observed. While photon correlation spectroscopy shows that the size of the polymer–surfactant–particle ensemble grows with added SDS, a reduction in the near-surface polymer concentration is measured by solvent relaxation NMR. Volume fraction profiles of the polymer layer extracted from small-angle neutron scattering experiments illustrate that the adsorbed polymer layer has become more diffuse and the polymer chains more elongated as a result of the addition of SDS. The total adsorbed amount is shown to decrease due to Coulombic repulsion between the surfactant–polymer complexes and between the complexes and the anionic silica surface.
Last edited: Friday September 10, 2010
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