- Confined soft matter: measuring the structure of lipid bilayers under confinement using neutron reflection. LLE Mears, R Barker, SB Abbott, SW Prescott, WM de Vos and RM Richardson. 25th International Liquid Crystal Conference, Dublin, Ireland, July 2014.
Abstract:
The adsorption of dopants at the surface of 5CB has been studied using neutron reflection. The
dopants were versions of 11OCB with partly fluorinated chains and the 5CB was interfaced with air
or with silica treated with fluorocarbon or hydrocarbon coatings. At the air interface, the F17-11OCB
adsorbed homeotropically and the amount increased on cooling into the nematic phase of 5CB. At
low temperatures, the adsorption from the nematic appeared to saturate at a bilayer. At the solid
interfaces, there was some evidence for a thin planar layer at the surface but most of the adsorbed
dopant was in the form of diffuse layers. In both cases an increase in dopant concentration caused
higher adsorbed amounts. For F17-11OCB, the amount absorbed was much greater for a fluorinated
coating as opposed to a hydrocarbon coated surface. Also no adsorption of the F3-11OCB could be
detected, suggesting that the adsorption process is driven by the oleophobic effect. The results
demonstrate that is possible to manipulate surface properties of liquid crystals using surfactant like
dopants.
Last edited: Friday September 10, 2010
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